Erratum to ``Determination of Henry`s law constants of
Transkript
ARTICLE IN PRESS Atmospheric Environment 40 (2006) 8096 www.elsevier.com/locate/atmosenv Erratum Erratum to ‘‘Determination of Henry’s law constants of organochlorine pesticides in deionized and saline water as a function of temperature’’ [Atmospheric Environment 40 (2006) 4538–4546] Banu Cetina, Serdar Ozerb, Aysun Sofuoglub, Mustafa Odabasia, a Department of Environmental Engineering, Faculty of Engineering, Dokuz Eylul University, Kaynaklar Campus, Buca 35160, Izmir, Turkey b Department of Chemical Engineering, Faculty of Engineering, Izmir Institute of Technology, Gulbahce-Urla 35460, Izmir, Turkey The publisher regrets that the second paragraph on p. 4545 was printed incorrectly. It now appears correctly, below. The presence of salts in aqueous solution affects the solubility of organic molecules, through the salting-out effect (Demou and Donaldson, 2002). The salting-out is defined as the decrease in aqueous solubility and increase in the activity coefficient observed for neutral non-polar compounds by dissolved inorganic salts. Ions in solution tightly bind several water molecules into hydration shells. This process (electrostriction), results in a reduction of the volume of the aqueous solution. A smaller aqueous volume results in less available water for cavity formation, and therefore less organic molecules are accommodated; their solubility decreases as a consequence (Schwarzenbach et al., 2002; Demou and Donaldson, 2002). The empirical relation for the effect of ionic strength on Henry’s law constant is described by Setschenow equation (Demou and Donaldson, 2002): DOI of original article: 10.1016/j.atmosenv.2006.04.009 Corresponding author. Tel.: +90 232 4127122; fax: +90 232 4530922. E-mail address: [email protected] (M. Odabasi). 1352-2310/$ - see front matter r 2006 Elsevier Ltd. All rights reserved. doi:10.1016/j.atmosenv.2006.09.024
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