safety data sheet poliroad

REV. NO./REPL. SDS GENERATED
SAFETY DATA SHEET
POLIROAD
1 IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
PRODUCT NO.
648
APPLICATION
Synthetic resin and solvent based cold road marking paint. Used for all kinds of traffic lines
amd markings on roads.
SUPPLIER
POLİSAN BOYA SAN. TİC. A.Ş.
DİLOVASI O.S.B.
1.KISIM LİMAN CAD. NO:7
DİLOVASI – KOCAELİ
TURKEY
Tel: +90 262 754 80 00
Fax: +90 262 754 74 34
www.polisan.com.tr
[email protected]
OHS DEPARTMENT
CONTACT PERSON
2 HAZARDS IDENTIFICATION
Flammable. Vapours may cause drowsiness and dizziness. Harmful: may cause lung damage if swallowed. Irritating to skin.
Possible risk of harm to the unborn child. Harmful: danger of serious damage to health by prolonged exposure through
inhalation. Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
CLASSIFICATION (1999/45)
Xn;R48/20, R65. Repr. Cat. 3;R63. Xi;R38. R52/53, R10, R67.
3 COMPOSITION/INFORMATION ON INGREDIENTS
Name
EC No.
CAS-No.
Content %
Classification (67/548/EEC)
ETHYL METHYL KETOXIME
202-496-6
96-29-7
< 1%
Carc. Cat. 3;R40 Xn;R21 R43 Xi;R41
ISO-BUTANOL
201-148-0
78-83-1
1-5%
R10 Xi;R37/38,R41 R67
ISOBUTYL METHYL KETONE
203-550-1
108-10-1
1-5%
F;R11 Xn;R20 Xi;R36/37 R66
< 1%
Repr. Cat. 1;R61. Xn;R65,R20/22.
Repr. Cat. 3;R62. N;R50/53.
R10,R33.
F;R11 Repr. Cat. 3;R63
Xn;R48/20,R65 Xi;R38 R67
R10 Xn;R20/21 Xi;R38
KURSUN
TOLUENE
203-625-9
108-88-3
25-40%
XYLENE
215-535-7
1330-20-7
< 1%
The Full Text for all R-Phrases is Displayed in Section 16
4 FIRST-AID MEASURES
GENERAL INFORMATION
Move the exposed person to fresh air at once. In all cases of doubt, or when symptoms persist, seek medical attention.
Never give anything by mouth to an unconcious person. Show this label or product container to the medically authorized
person.
NOTES TO THE PHYSICIAN
No recommendation given, but first aid may still be required in case of accidental exposure, inhalation or ingestion of this
chemical. If in doubt, GET MEDICAL ATTENTION PROMPTLY!
INHALATION
Remove victim immediately from source of exposure. Move into fresh air and keep at rest. Get medical attention if any
discomfort continues. If respiratory problems, artificial respiration/oxygen.
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INGESTION
DO NOT induce vomiting. Get medical attention immediately.
SKIN CONTACT
Remove contaminated clothing immediately and wash skin with soap and water. Get medical attention if any discomfort
continues.
EYE CONTACT
Promptly wash eyes with plenty of water while lifting the eye lids. Rinse with water. Contact physician if discomfort
continues.
5 FIRE-FIGHTING MEASURES
EXTINGUISHING MEDIA
Extinguish with alcohol-resistant foam, carbon dioxide, dry powder or water fog.
SPECIAL FIRE FIGHTING PROCEDURES
Avoid breathing fire vapours.
SPECIFIC HAZARDS
Yangin sonucunda yogun siyah bir duman olusabilir. Yanma sonucunda olusan gaz , dumanlar saglik tehlikesi yaratabilir
.Itfaiyeciler, bu ürünlere karsi pozitif basinçli solunum cihazi kulanmalidir. Isiya maruz kalmis ambalajlar su ile
sogutulmalidir. Yangin söndürmeden dolayi akan sülarin kanalizasyonu veya su kanallarina karismalarina izin
verilmemelidir.
PROTECTIVE MEASURES IN FIRE
Wear full protective clothing.
6 ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS
Avoid inhalation of vapours and contact with skin and eyes. Provide adequate ventilation. Wear protective clothing as
described in Section 8 of this safety data sheet.
ENVIRONMENTAL PRECAUTIONS
Avoid discharge into drains, water courses or onto the ground. Collect and dispose of spillage as indicated in section 13.
Contain spillages with sand, earth or any suitable adsorbent material.
SPILL CLEAN UP METHODS
Ensure that waste and contaminated materials are collected and removed from the work area as soon as possible in a
suitably labelled container.
7 HANDLING AND STORAGE
USAGE PRECAUTIONS
Avoid spilling, skin and eye contact. Keep away from heat, sparks and open flame. Risk of vapour concentration on the
floor and in low-lying areas. Avoid eating, drinking and smoking when using the product. Avoid inhalation of vapours.
Karisim elektrostatik olarak alevlenebilir. Exproof elektrikli cihazlarýn bulundugu ortamlarda kullanilmasi ve depolanmasi
uygulandir
USAGE DESCRIPTION
Use the product according to its Technical Data Sheet or instructions written on the label
STORAGE PRECAUTIONS
Flammable/combustible - Keep away from oxidisers, heat and flames. Take precautionary measures against static
discharges. Store in tightly closed original container in a dry, cool and well-ventilated place. Tavsiye edilen ic ambalaj
malzemeleri , celik, PE, PP ve teflon Ic ambalaj malzemesi olarak dogal kaucuk, butil kaucuk ve polistiren uygun degildir
Store in closed original container at temperatures between 5°C and 30°C.
STORAGE CLASS
Flammable liquid storage.
8 EXPOSURE CONTROLS/PERSONAL PROTECTION
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TWA - 8 Hrs
REV. NO./REPL. SDS GENERATED
Name
STD
STEL - 15 Min
ISO-BUTANOL
WEL
50 ppm
154 mg/m3
75 ppm
231 mg/m3
ISOBUTYL METHYL KETONE
WEL
TOLUENE
WEL
XYLENE
WEL
50
ppm(Sk)
50
ppm(Sk)
50
ppm(Sk)
208
mg/m3(Sk)
191
mg/m3(Sk)
220
mg/m3(Sk)
100
ppm(Sk)
150
ppm(Sk)
100
ppm(Sk)
416
mg/m3(Sk)
574
mg/m3(Sk)
441
mg/m3(Sk)
Notes
WEL = Workplace Exposure Limit.
PROTECTIVE EQUIPMENT
ENGINEERING MEASURES
Provide adequate ventilation, including appropriate local extraction, to ensure that the defined occupational exposure limit
is not exceeded.
RESPIRATORY EQUIPMENT
In case of inadequate ventilation and work of brief duration, use suitable respiratory equipment.
HAND PROTECTION
Barrier cream applied before work may make it easier to clean the skin after exposure, but does not prevent absorption
through the skin. Nitrile gloves are recommended. Neoprene gloves are recommended. Latex Eldiven Kullanilabilir
EYE PROTECTION
Wear splash-proof eye goggles to prevent any possibility of eye contact.
OTHER PROTECTION
AVOID ALL SKIN AND RESPIRATORY CONTACT!
HYGIENE MEASURES
DO NOT SMOKE IN WORK AREA!
SKIN PROTECTION
Dogal iplikten veya yüksek isiya dayanikli sentetik iplikten yapilmis antistatic giysi giyiniz
ENVIRONMENTAL EXPOSURE CONTROLS
Look upto Chapter 6
9 PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE
Clear liquid.
COLOUR
Colourless.
ODOUR
Characteristic
BULK DENSITY
FLASH POINT (°C)
FLAMMABILITY LIMIT LOWER(%)
FLAMMABILITY LIMIT UPPER(%)
0,861 - 0,867 kg/m3
< 21 CC (Closed cup).
1,1
12,8
10 STABILITY AND REACTIVITY
CONDITIONS TO AVOID
Avoid heat, flames and other sources of ignition. Iyi bir dogal havalandirma ve gerekli ise yerden egzost havalandirmsi
saglanmalidir.
MATERIALS TO AVOID
Keep away from oxidizing agents, strongly alkaline and strongly acid materials in order to avoid exothermic reactions
HAZARDOUS DECOMPOSITION PRODUCTS
In case of fire, toxic gases (CO, CO2, NOx) may be formed.
11 TOXICOLOGICAL INFORMATION
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REV. NO./REPL. SDS GENERATED
INHALATION
May cause irritation to the respiratory system. Vapours may cause drowsiness and dizziness.
INGESTION
There is no information about experimantal datas of product
SKIN CONTACT
Prolonged or repeated exposure may cause severe irritation.
EYE CONTACT
Splashes may irritate.
12 ECOLOGICAL INFORMATION
ECOTOXICITY
There are no data on the ecotoxicity of this product.
MOBILITY
Not applied
BIOACCUMULATION
No data available on bioaccumulation.
DEGRADABILITY
There is no information about experimantal datas of product
13 DISPOSAL CONSIDERATIONS
GENERAL INFORMATION
Waste to be treated as controlled waste. Disposal to licensed waste disposal site in accordance with local Waste Disposal
Authority.
DISPOSAL METHODS
Incinerate liquid and contaminated solids in accordance with local, state
and federal regulations.
14 TRANSPORT INFORMATION
FLAMMABLE
LIQUID
3
PROPER SHIPPING NAME
PAINT RELATED MATERIAL
ENVIRONMENTALLY
HAZARDOUS
SUBSTANCE/MARINE
POLLUTANT
UN NO. ROAD
No.
ADR CLASS NO.
3
ADR CLASS
Class 3: Flammable liquids.
ADR PACK GROUP
II
TUNNEL RESTRICTION
CODE
HAZARD No. (ADR)
(D/E)
ADR LABEL NO.
3
HAZCHEM CODE
•3YE
UN NO. SEA
1263
IMDG CLASS
3
IMDG PACK GR.
II
EMS
F-E, S-E
UN NO. AIR
1263
AIR CLASS
3
1263
33
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AIR PACK GR.
REV. NO./REPL. SDS GENERATED
II
15 REGULATORY INFORMATION
LABELLING
Harmful
CONTAINS
TOLUENE
RISK PHRASES
R10
R38
R48/20
R52/53
R63
R65
R67
Flammable.
Irritating to skin.
Harmful: danger of serious damage to health by prolonged exposure
through inhalation.
Harmful to aquatic organisms, may cause long-term adverse effects
in the aquatic environment.
Possible risk of harm to the unborn child.
Harmful: may cause lung damage if swallowed.
Vapours may cause drowsiness and dizziness.
SAFETY PHRASES
S24
S36/37
S51
S60
S62
P14
Avoid contact with skin.
Wear suitable protective clothing and gloves.
Use only in well-ventilated areas.
This material and its container must be disposed of as hazardous
waste.
If swallowed, do not induce vomiting: seek medical advice
immediately and show this container or label.
Contains ETHYL METHYL KETOXIME. May produce an allergic
reaction.
EU DIRECTIVES
System of specific information relating to Dangerous Preparations. 2001/58/EC.
16 OTHER INFORMATION
INFORMATION SOURCES
This SDS is prepared based on the information received from the raw material owner.
REVISION COMMENTS
NOTE: Lines within the margin indicate significant changes from the previous revision.
ISSUED BY
Nuray CIKCIKLI
SDS NO.
618
DATE
15.08.2005
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POLIROAD
RISK PHRASES IN FULL
R33
R10
R20/22
R20/21
R20
R21
R52/53
R48/20
R65
R11
R36/37
R37/38
R38
R40
R61
R43
R63
R62
R66
R41
R67
R50/53
REV. NO./REPL. SDS GENERATED
Danger of cumulative effects.
Flammable.
Harmful by inhalation and if swallowed.
Harmful by inhalation and in contact with skin.
Harmful by inhalation.
Harmful in contact with skin.
Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
Harmful: danger of serious damage to health by prolonged exposure through inhalation.
Harmful: may cause lung damage if swallowed.
Highly flammable
Irritating to eyes and respiratory system.
Irritating to respiratory system and skin.
Irritating to skin.
Limited evidence of a carcinogenic effect.
May cause harm to the unborn child.
May cause sensitisation by skin contact.
Possible risk of harm to the unborn child.
Possible risk of impaired fertility.
Repeated exposure may cause skin dryness or cracking.
Risk of serious damage to eyes.
Vapours may cause drowsiness and dizziness.
Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
DISCLAIMER
This information relates only to the specific material designated and may not be valid for such material used in combination with any
other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate and reliable as of
the date indicated. However, no warranty guarantee or representation is made to its accuracy, reliability or completeness. It is the
user's responsibility to satisfy himself as to the suitability of such information for his own particular use.
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